Hollow nanostructures for the functional assembly of chemical groups with inner surface geometry and regulable stoichiometry enable steric design of interior reaction centers. Herein we report a metal–macrocycle framework (MMF) that forms single-crystalline nanochannels with five distinct enantiomeric pairs of guest binding pockets. During crystal-soaking experiments, the MMF .
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Pentacyclic Nano-Trefoil: ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag + / 1 molar ratio. It was also revealed that the 3:5 trefoil complex could encapsulate benzene and benzene- d 6 selectively in solid-state.
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Pentacyclic Nano-Trefoil. Article. Sep 2020 ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic .
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Seven double-armed cyclens bearing two aromatic side-arms, at the 1- and 7-positions of the cyclens, were prepared via three steps from dimethyl 2,2′-iminodiacetate. The X-ray structures of the Ag+ complexes and Ag+-ion-induced 1H NMR spectral changes suggest that the two aromatic side-arms cover the Ag+ ions incorporated in the ligand cavities, as if the aromatic ring .
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Pentacyclic Nano-Trefoil: ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag + / 1 molar ratio. It was also revealed that the 3:5 trefoil complex could encapsulate benzene and benzene- d 6 selectively in solid-state.
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Sep 24, 2020· Pentacyclic Nano-Trefoil. Abstract Tetra-armed cyclen ( 1 ) bearing two 4-(4'-pyridyl)benzyl and two 3,5-difluorobenzyl groups and its Ag + complexes were prepared and structurally characterized. The complex formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil ...
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The reversible structural transformation between 2:2 (1/Ag+) dimer and 3:5 (1/Ag+) pentacyclic trefoil complexes based on the tetra‐armed cyclen with two 4‐(4′‐pyridyl)benzyl and two 3,5‐difluorobenz...
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Pentacyclic Nano‐Trefoil. 126th KCS meeting October 19-21, 2020, online. ISMSC 2021 August 1-6, 2021, Oregon USA. UPCOMING EVENTS. Pacifichem 2021 December 16-21, 2021, Hawaii USA . DETAILS. DETAILS. DETAILS. RECENT NEWS. 2020. 10. 09 Our homepage open! Inorganic and Nanomaterial Chemistry Laboratory.
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Pentacyclic Nano‐Trefoil. The reversible structural transformation between 2:2 (1/Ag+) dimer and 3:5 (1/Ag+) pentacyclic trefoil complexes based on the tetra‐armed cyclen with two 4‐(4′‐pyridyl)benzyl and two 3,5‐difluorobenzyl groups is reported. Also, the selective separation of a benzene molecule in the cavity of the trefoil was ...
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Pentacyclic Nano-Trefoil. Article. Sep 2020 ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic .
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Отображение 1 - 20 из 1,958 для поиска: 'Eunji Lee', время запроса: 1.05сек.
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Pentacyclic Nano‐Trefoil. Journal content | Sep 21, 2020 Recommendations: n/a. Published in. Angewandte Chemie Int Ed, Wiley-VCH Content. Tetra‐armed cyclen ( 1 ) bearing two 4‐(4'‐pyridyl)benzyl and two 3,5‐difluorobenzyl groups and its Ag + complexes were prepared and structurally characterized. ...
Get pricePentacyclic Nano‐Trefoil. By Huiyeong Ju, Eunji Lee, Yumiko Tsuruoka, Miho Hyano. onlinelibrary.wiley — Communication Yoichi HabataCorresponding Author E-mail address: [email protected] Toho University, Chemistry, 2-2-1, Miyama, 274-8510 Funabashi, JAPAN Search for more ...
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Pentacyclic Nano-Trefoil. Article. Sep 2020 ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic .
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Pentacyclic Nano-Trefoil. @article{Ju2020PentacyclicN, title={Pentacyclic Nano-Trefoil.}, author={Huiyeong Ju and Yumiko Tsuruoka and Miho Hyano and Eunji Lee and Ki-Min Park and Mari Ikeda and Jun-Ichi Ishii and S. Kuwahara and Yoichi Habata}, journal={Angewandte Chemie}, year={2020} }
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Pentacyclic Nano‐Trefoil. The reversible structural transformation between 2:2 (1/Ag+) dimer and 3:5 (1/Ag+) pentacyclic trefoil complexes based on the tetra‐armed cyclen with two 4‐(4′‐pyridyl)benzyl and two 3,5‐difluorobenzyl groups is reported. Also, the selective separation of a benzene molecule in the cavity of the trefoil was ...
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Pentacyclic Nano-Trefoil. Article. Sep 2020 ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic .
Get pricePentacyclic Nano-Trefoil. Angewandte Chemie International Edition ( IF 12.959) Pub Date : 2020-09-21, DOI: 10.1002/anie.202010436 Huiyeong Ju,Yumiko Tsuruoka,Miho Hyano,Eunji Lee,Ki-Min Park,Mari Ikeda,Jun-Ichi Ishii,Shunsuke Kuwahara,Yoichi Habata
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Tetra-armed cyclens bearing aromatic side arms were prepared by the reductive amination of cyclen with substituted benzaldehydes. When equimolar amounts of Ag+ ions were added to the ligands, the aromatic rings covered the Ag+ ions incorporated in the ligand cavities, as if the aromatic ring "petals" caught the Ag+ ions in the way an insectivorous plant (Venus flytrap) .
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Pentacyclic Nano‐Trefoil Angew. Chem. Int. Ed. (IF 12.959 ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag + / 1 molar ratio. It was also revealed that the 3:5 trefoil complex
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Pentacyclic Nano-Trefoil. Article. Sep 2020 ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic .
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Pentacyclic Nano-Trefoil. Angew. Chem. Int. Ed. (IF 12.959) Pub Date : 2020-09-21 Huiyeong Ju,Yumiko Tsuruoka,Miho Hyano,Eunji Lee,Ki-Min Park,Mari Ikeda,Jun-Ichi Ishii,Shunsuke Kuwahara,Yoichi Habata ：2020-11-03 Continuous Flow Sodiation of Substituted Acrylonitriles, Alkenyl Sulfides and Acrylates ...
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Get pricePentacyclic Nano‐Trefoil Tetra‐armed cyclen ( 1 ) bearing two 4‐(4'‐pyridyl)benzyl and two 3,5‐difluorobenzyl groups and its Ag + complexes were prepared and structurally characterized. The complex formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil ...
Get priceJan 08, 2021· このか1つだけにきわったペルヒドロアズレン-d 1 、スペクトル(vcd)がされ、からられるものとだいたいするのだとか。なお、ナトリウムdをとするはほぼゼロ。
Get pricePentacyclic Nano-Trefoil Angewandte Chemie (International ed. in English) （） 2020/09/21: 4. Argentivorous Molecules Exhibiting Highly Selective Silver(I) Chiral Enhancement. Inorganic chemistry 59(18),pp.13435-13441 （） 2020/08: 5.
Get pricePentacyclic Nano‐Trefoil Angew. Chem. Int. Ed. (IF 12.959 ... formed between 1 and Ag + undergoes a reversible structural transformation between a 2:2 dimeric complex and a 3:5 pentacyclic trefoil complex with changes in the Ag + / 1 molar ratio. It was also revealed that the 3:5 trefoil complex
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Pentacyclic Nano-Trefoil Angewandte Chemie (International ed. in English) （） 2020/09/21: 4. Argentivorous Molecules Exhibiting Highly Selective Silver(I) Chiral Enhancement. Inorganic chemistry 59(18),pp.13435-13441 （） 2020/08: 5.
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Pentacyclic Nano-Trefoil. Angewandte Chemie International Edition ( IF 12.959) Pub Date : 2020-09-21, DOI: 10.1002/anie.202010436 Huiyeong Ju,Yumiko Tsuruoka,Miho Hyano,Eunji Lee,Ki-Min Park,Mari Ikeda,Jun-Ichi Ishii,Shunsuke Kuwahara,Yoichi Habata
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Pentacyclic Nano‐Trefoil. By Huiyeong Ju, Eunji Lee, Yumiko Tsuruoka, Miho Hyano. onlinelibrary.wiley — Communication Yoichi HabataCorresponding Author E-mail address: [email protected] Toho University, Chemistry, 2-2-1, Miyama, 274-8510 Funabashi, JAPAN Search for more ...
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Hetero-bifunctional ligands can pave the way for elaborate metallo-supramolecular systems and are also useful for combining metal–ligand bonding with other types of noncovalent interactions. We synthesized two new pyridyl-acetylacetonate ligands, 3-(4-(pyridin-4-yl)phenyl)pentane-2,4-dione (L1) and 3-(4-(pyridin-4-ylethynyl)phenyl)pentane-2,4-dione (L2), and explored their .
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